The file browser consists of a list of categories, each containing one or more images. Click on a category header to open or close it, and click on an image to either view it or add it to the download queue. (If it's on disk or not, respectively.)

Diiva uses small icon badges to inform you about a file's state. There are four of these badges, described below. Categories are badged to reflect their contents; if a category contains at least one image that is queued, for example, that category's header qill have a "queued" badge on it. If all of the files in a category are of the same state, the category's header will have a single centered badge. (All of the Edward Hopper images are on disk, for example.)

On Disk - This file has been downloaded, and it is filed on your drive. Click to view it.
Marked for Deletion - This file is on disk as well, but it will be deleted when you quit Diiva. (You can toggle the delete mark with either contextual menus or the keyboard.)
Queued - This file is currently in the download queue. Clicking it will remove it from the queue.
Downloading - This file is in the process of being downloaded. Click it to watch its progress.